The Origins of Sorbitan: From Sorbitol to Emulsifier
To understand if sorbitan is made from corn, one must first look at its precursor: sorbitol. Sorbitol is a sugar alcohol found naturally in many fruits, including apples, pears, and peaches. However, for commercial applications, it is more economically viable to produce sorbitol from other sources, most commonly from the hydrogenation of glucose. This glucose is often sourced from cornstarch, but can also come from other plant-based starches like potatoes or tapioca.
Sorbitan itself is not a raw ingredient but a processed compound. It is produced by dehydrating sorbitol, which removes a water molecule to create an anhydrous cyclic ether. The resulting compound, sorbitan, is then typically esterified with fatty acids, such as stearic, oleic, or lauric acid, to create a range of emulsifiers known as sorbitan esters. These are used to mix ingredients that normally do not combine, like oil and water, in products from food to cosmetics.
The Production Process: From Glucose to Sorbitan Esters
The manufacturing of sorbitan esters follows a multi-stage chemical process. It begins with the source material for the glucose.
Step 1: Producing Sorbitol from Glucose
Glucose is the starting point for sorbitol production. When derived from corn, the cornstarch is broken down into glucose syrup. This glucose is then reacted with hydrogen gas under pressure, with the aid of a catalyst, to produce sorbitol.
Step 2: Dehydrating Sorbitol to Sorbitan
Next, the sorbitol is heated under specific conditions to undergo a dehydration reaction. This process removes water, converting the sorbitol into a mixture of cyclic ethers, collectively known as sorbitan.
Step 3: Esterification with Fatty Acids
Finally, the sorbitan is reacted with a fatty acid (or multiple fatty acids) in a process called esterification. The specific fatty acid used determines the final properties of the sorbitan ester. Importantly, the source of these fatty acids can vary:
- Vegetable-based: Fatty acids can be sourced from vegetable oils, which makes the final sorbitan ester vegan-friendly.
- Animal-based: Alternatively, fatty acids can be derived from animal fats, in which case the end product would not be suitable for a vegan diet.
This is a crucial point for consumers, as the ultimate vegan or non-vegan status of a sorbitan product depends on the sourcing of the fatty acid component, not just the initial sorbitol.
Sorbitan and Your Nutrition Diet
Sorbitan esters, such as sorbitan monostearate (Span 60) and polysorbates (like Tween 80), are found in a wide variety of foods. Their primary function is as an emulsifier and stabilizer, helping to improve texture and shelf life. For example, they are widely used in baked goods, chocolates, and instant dry yeast to enhance consistency. For those concerned about their nutrition diet, it's important to understand what these additives are.
Dietary Considerations
- Vegan Diet: As noted, a product containing sorbitan isn't necessarily vegan. Individuals following a vegan diet should confirm with the manufacturer that the fatty acid used is plant-based.
- Corn Allergies: For individuals with corn allergies, the presence of sorbitan can be a concern. However, manufacturers state that the processing to create sorbitol and subsequently sorbitan eliminates the plant protein, which is typically the source of allergic reactions. While the risk is low, people with sensitivities should proceed with caution and consult a healthcare professional.
- Safety: The U.S. Food and Drug Administration (FDA) lists sorbitan esters as Generally Recognized As Safe (GRAS) for use in food products. They are considered non-toxic and non-irritant when ingested in typical food quantities.
Common Food Uses of Sorbitan Esters
- Baked Goods: Used to improve dough conditioning and crumb texture.
- Chocolates: Act as an anti-blooming agent, preventing fat crystals from rising to the surface.
- Instant Yeast: Coats yeast cells to protect them from oxygen and aid in rehydration.
- Desserts: Stabilize creamy fillings and toppings.
- Beverage Whiteners: Helps dry ingredients dissolve smoothly in liquids.
Sorbitan vs. Sorbitol: A Comparison
To avoid confusion, here's a quick comparison of the two related compounds.
| Feature | Sorbitol | Sorbitan | 
|---|---|---|
| Chemical Nature | Sugar alcohol (Polyol) | Dehydrated form of sorbitol (Anhydride) | 
| Form | Crystalline solid | Can be a mixture of isomers | 
| Source | Produced from the hydrogenation of glucose (often from cornstarch) or found naturally in fruits | Produced by dehydrating sorbitol | 
| Primary Use | Sweetener, laxative, humectant | Intermediate compound for sorbitan esters | 
| Function in Food | Sugar substitute, texture agent | Emulsifier, stabilizer (as an ester) | 
Conclusion: Is Sorbitan Made From Corn?
In conclusion, is sorbitan made from corn? Yes, it can be, but it is not exclusively a corn-derived ingredient. Sorbitan is a processed compound created from sorbitol, and commercial sorbitol is often produced using corn-derived glucose. However, sorbitan can also originate from sorbitol derived from other starches, such as potatoes. The final sorbitan ester's characteristics and suitability for specific diets also depend on the source of the fatty acids used in its synthesis. While the link to corn exists for many commercial products, the extensive processing involved means that concerns regarding corn allergens are typically minimal. For those on a vegan nutrition diet, confirming the source of the fatty acid is the key to ensuring dietary compliance.