Sources of Naturally Occurring Lithium in Drinking Water
Lithium, a naturally occurring alkali metal, enters drinking water sources primarily through geological processes. The concentration depends heavily on the interaction between water and mineral-rich rocks and soil.
Geological and Groundwater Sources
- Rock and Soil Interaction: As groundwater permeates through subterranean rock fissures, it leaches minerals, including lithium salts, from the surrounding geology. Areas with lithium-bearing minerals, such as granite and pegmatites, and regions with geothermal activity or saline waters, often have higher levels.
- Geographic Variation: A 2024 USGS study found that lithium concentrations are higher in groundwater that supplies wells in arid regions of the western and southwestern U.S. These include states like Montana, Wyoming, North Dakota, South Dakota, Colorado, Utah, Nevada, Arizona, New Mexico, and Texas.
- Arid vs. Humid Regions: Higher concentrations in arid regions are attributed to factors such as lower rainfall and higher rates of evaporation, which can concentrate minerals in remaining groundwater. In contrast, humid regions tend to have lower levels.
Industrial and Anthropogenic Sources
While natural sources are the primary contributors, some industrial activities can also influence local water quality. As the demand for lithium-ion batteries increases, potential contamination from mining operations, manufacturing, or landfill runoff becomes a factor to monitor. The U.S. Environmental Protection Agency (EPA) is gathering data on lithium under the Unregulated Contaminant Monitoring Rule (UCMR5) to assess its prevalence.
Specific Bottled Mineral Waters
Some bottled mineral waters are known to have naturally higher concentrations of lithium. For consumers looking for this specific mineral, these brands may be of interest, though concentrations vary and are typically much lower than therapeutic doses.
- Vichy Catalan (Spain): Sourced from a thermal spring in Girona, this naturally carbonated water is among the highest in lithium content, with over 1000 µg/L reported in some studies.
- Gerolsteiner (Germany): This popular sparkling mineral water contains around 0.13 mg/L (130 µg/L) of lithium.
- San Pellegrino (Italy): This well-known Italian mineral water also has detectable levels, reported at approximately 0.12 ppm (120 µg/L).
- Lithia Spring Water (USA): This American brand is sourced from historic springs in Georgia and is known for its high mineral content, including lithium.
- Vidago (Portugal): An example of an exceptionally high-lithium water, with concentrations reaching 2.2 mg/L (2200 µg/L).
Health Implications of Low-Dose Lithium in Water
Research into the health effects of naturally occurring, low-dose lithium is ongoing and has yielded mixed but intriguing results.
Potential Benefits and Observational Studies
Ecological studies have observed an inverse correlation between the amount of lithium in a region's drinking water and certain mental health metrics.
- Lower Suicide Rates: A 2020 meta-analysis found that higher concentrations of lithium in drinking water were associated with lower suicide rates in the studied populations.
- Reduced Dementia Risk: Studies in regions with higher lithium levels have suggested a lower incidence of dementia.
Potential Risks and Concerns
While therapeutic doses of lithium for bipolar disorder have known side effects, the health effects of chronic, low-dose exposure from drinking water are less clear and require further research.
- Increased Autism Risk: A 2023 study from UCLA-led researchers in Denmark found a moderately higher risk of autism in children whose mothers had higher levels of lithium in their household tap water during pregnancy. The authors emphasized that this was a correlation, not proof of causation, and called for further investigation.
- Thyroid Function: Research has indicated that environmental lithium exposure from drinking water and other sources may affect thyroid function, consistent with side effects seen at therapeutic doses.
- Ethical Considerations: The potential for widespread health impacts from low-dose exposure raises ethical questions about water fortification and the need for more robust, randomized studies.
Comparison of Natural Lithium Sources
| Source | Typical Concentration | Geographic Distribution | Regulation Status (US) | Primary Consideration |
|---|---|---|---|---|
| Tap Water | Varies widely (e.g., <1 to 1700 µg/L) | Varies geologically; higher in western US groundwater | Unregulated, currently monitored under UCMR5 | Geographic location dictates level; source of widespread, low-dose exposure |
| Bottled Mineral Water | Highly variable by brand (e.g., Vichy Catalan >1000 µg/L) | Varies by source; brands often originate from specific springs | Generally considered a food product; labels may list minerals | Allows for targeted consumption of higher-lithium water; more expensive |
| Supplements | Standardized dose; typically in mg range | N/A | Regulated by FDA as dietary supplement | Controlled dosage; for therapeutic use under medical supervision |
Conclusion
Lithium is a naturally occurring element found in drinking water, with levels influenced by regional geology, particularly in arid areas. While some bottled mineral waters contain notable amounts, tap water concentrations can vary significantly depending on the local water source, with arid western US regions often having higher levels. Ecological studies suggest potential links between low-dose lithium and mental health outcomes, including lower suicide rates, though causality remains unproven. Conversely, recent research has raised concerns about potential risks, such as the association between higher prenatal exposure and increased autism risk. As the EPA continues to gather data through UCMR5, it is crucial for individuals to understand their water sources and for further research to clarify the long-term health implications of low-dose lithium exposure. Ultimately, for those interested in their water's mineral content, checking with local water utilities or referencing databases like the Environmental Working Group (EWG) can provide more information.
Further Reading
For more detailed information on U.S. groundwater quality and contaminant monitoring, refer to official publications from the U.S. Geological Survey (USGS). USGS News Release on Lithium in Groundwater