The Core Chemical Differences: Elemental vs. Compounds
To understand how magnesium reacts with carbonated water, it is crucial to distinguish between elemental magnesium (the pure metal) and magnesium compounds, such as magnesium hydroxide (Milk of Magnesia).
Elemental Magnesium Metal and Carbonated Water
At room temperature, elemental magnesium metal, which is a reactive alkaline earth metal, has a protective oxide layer that prevents it from having a visible, rapid reaction with water, including carbonated water. The slow reaction produces magnesium hydroxide and hydrogen gas, but the resulting magnesium hydroxide layer insulates the rest of the metal from further contact with water, effectively stopping the process. However, the presence of carbonic acid (produced when CO₂ dissolves in water) slightly accelerates the reaction, but it is not a dramatic or immediate change.
Magnesium Hydroxide and Carbonated Water
The most notable and practical reaction occurs when a magnesium compound, specifically magnesium hydroxide, is mixed with carbonated water. This is the basis for many homemade and commercially available magnesium bicarbonate supplements. The reaction is straightforward and involves an acid-base neutralization:
$Mg(OH)_2(s) + 2CO_2(aq) \to Mg(HCO_3)_2(aq)$
In this equation, magnesium hydroxide, a sparingly soluble base, reacts with the carbonic acid ($H_2CO_3$), which is formed by the dissolved carbon dioxide ($CO_2$) in the water. The products are water and magnesium bicarbonate ($Mg(HCO_3)_2$), a compound that exists only in aqueous solution and is highly soluble. The reaction is visually apparent as the cloudy, white magnesium hydroxide suspension becomes a clear solution as the magnesium bicarbonate is formed.
Comparison of Magnesium Reactivity with Carbonated Water
| Feature | Elemental Magnesium Metal (Mg) | Magnesium Hydroxide (Mg(OH)₂) |
|---|---|---|
| Starting Material | Solid, pure metal, often as flakes or strips. | White powder or liquid suspension (Milk of Magnesia). |
| Reacts with Carbonated Water? | Minimally and very slowly due to a passivating oxide layer. | Yes, a purposeful and well-known reaction. |
| End Product | Magnesium hydroxide and hydrogen gas, but reaction is stifled. | Magnesium bicarbonate ($Mg(HCO_3)_2$), a soluble salt. |
| Reaction Speed | Extremely slow at room temperature. | Quick, resulting in a clear solution within minutes to hours. |
| Safety & Practicality | Not practical for creating a supplement; can be highly reactive when heated (e.g., in fire). | Safe for preparing supplements when done correctly, resulting in a gentle, bioavailable form. |
| Visible Signs of Reaction | Few, small bubbles forming very slowly over a long period. | Initial fizzing and bubbling, followed by the solution clearing as the solid dissolves. |
Practical Applications: Creating a Bioavailable Supplement
Creating your own magnesium bicarbonate water is a known method for increasing magnesium intake in a highly absorbable form. The process involves mixing magnesium hydroxide powder with unflavored carbonated water. The resulting solution is often stored in a sealed bottle to maintain its stability, as magnesium bicarbonate will slowly decompose back into insoluble magnesium carbonate and carbon dioxide if exposed to air.
Steps for a DIY Magnesium Bicarbonate Solution:
- Gather Ingredients: Obtain food-grade magnesium hydroxide powder and plain, unflavored carbonated water.
- Prepare the Container: Use a clean, sealed glass bottle. Pour out a small amount of the carbonated water to create headspace for the reaction.
- Combine: Add a measured amount of magnesium hydroxide powder to the bottle. A common ratio is 1 teaspoon of powder per liter of water.
- Shake and Dissolve: Seal the bottle quickly and shake vigorously for 1-2 minutes. The mixture will turn cloudy as the powder suspends.
- Wait and Store: Place the bottle in the refrigerator. The solution will gradually become clear over several hours as the reaction completes and the magnesium bicarbonate dissolves completely.
The Bioavailability Advantage
One of the main reasons for creating magnesium bicarbonate water is its superior bioavailability. Many common magnesium supplements, like magnesium oxide, have low absorption rates. The liquid magnesium bicarbonate bypasses this issue and is absorbed efficiently, making it gentle on the stomach and effective for supplementation. This makes it a popular option for those seeking to boost their magnesium levels without the common laxative side effects associated with other forms.
Conclusion: The Chemistry is Context-Dependent
The question of whether magnesium reacts with carbonated water is answered by specifying the form of magnesium. Elemental metal magnesium has only a negligible reaction due to its protective oxide layer. In contrast, the intentional mixing of magnesium hydroxide with carbonated water, which contains carbonic acid, results in a well-understood chemical reaction. This process produces magnesium bicarbonate, a highly absorbable and stomach-friendly form of magnesium that is popular for supplementation. Understanding this distinction is key for anyone interested in the chemistry or practical application of these compounds.
For additional scientific context on magnesium and its bioavailability from different sources, see this related study: Predicting and Testing Bioavailability of Magnesium Supplements.