What do disaccharides include? The composition of double sugars
Disaccharides are carbohydrates often called 'double sugars' because they are made of two linked monosaccharide units. This connection, a glycosidic bond, forms through dehydration synthesis, removing a water molecule. The specific monosaccharides and the bond type determine properties like sweetness and digestibility. The general formula for many is C12H22O11.
The most common disaccharides and their components
Several disaccharides are common in human diets and everyday foods.
Sucrose (Table Sugar)
Sucrose is common table sugar, found in sugar cane, sugar beets, and fruits.
- Composition: Glucose and fructose.
- Glycosidic Bond: $\alpha(1\to2)\beta$.
- Properties: It is a non-reducing sugar.
Lactose (Milk Sugar)
Lactose is the main carbohydrate in mammal milk.
- Composition: Galactose and glucose.
- Glycosidic Bond: $\beta(1\to4)$.
- Digestion: Requires the enzyme lactase; lack of it causes lactose intolerance.
Maltose (Malt Sugar)
Maltose is less common, formed during grain germination and starch breakdown.
- Composition: Two glucose units.
- Glycosidic Bond: $\alpha(1\to4)$.
- Occurrence: Used in candy and found in beers.
Other notable disaccharides
- Trehalose: Two glucose molecules with a different link, found in yeast and insects.
- Cellobiose: Two glucose units with a $\beta(1\to4)$ bond, from cellulose breakdown.
- Lactulose: A synthetic fructose-galactose disaccharide used as a laxative.
The process of forming and breaking down disaccharides
Disaccharides are vital for metabolism, acting as transport and energy molecules.
Formation: Dehydration Synthesis
Monosaccharides combine via dehydration synthesis, forming a glycosidic bond and releasing water. This creates compact molecules for transport and storage.
Digestion: Hydrolysis
For energy use, disaccharides are hydrolyzed back into monosaccharides by adding water. Enzymes in the small intestine, like sucrase, lactase, and maltase, facilitate this breakdown. The resulting monosaccharides are absorbed into the bloodstream. Humans cannot digest certain $\beta$-glycosidic bonds, such as those in cellulose.
Comparison of common disaccharides
| Disaccharide | Monosaccharide Units | Glycosidic Bond | Common Source | Nutritional Function | |
|---|---|---|---|---|---|
| Sucrose | Glucose + Fructose | $\alpha(1\to2)\beta$ | Sugar cane, sugar beets, fruits | Energy source, sweetener | |
| Lactose | Galactose + Glucose | $\beta(1\to4)$ | Milk and dairy products | Energy source for infants | |
| Maltose | Glucose + Glucose | $\alpha(1\to4)$ | Germinating grains, starch digestion | Energy source | 
Conclusion: The fundamental role of disaccharides
Disaccharides are fundamental to nutrition and biochemistry, composed of two simple sugar units. Common examples like sucrose, lactose, and maltose illustrate how these double sugars serve as crucial energy sources. They are broken down into monosaccharides in the small intestine via enzymatic hydrolysis, providing fuel for the body. Understanding their types, sources, and digestion is key to dietary choices. For more, see the Disaccharide - Wikipedia entry.