Agar Agar vs. Cornstarch: The Fundamental Difference
At first glance, both agar agar and cornstarch appear to be simple white powders used for thickening. However, their origin and chemical composition are fundamentally different, leading to unique behaviors in cooking and baking.
What is Agar Agar?
Agar agar is a translucent, plant-based gelling agent extracted from red algae. It is a polysaccharide, a carbohydrate composed of long chains of sugar molecules, and is a popular vegan alternative to gelatin, which comes from animal collagen. Agar is sold in powder, flake, or bar form, with the powder being the most potent and easiest to dissolve. Agar gels are much firmer and more heat-stable than gelatin-based gels and have a unique, rubbery texture.
What is Cornstarch?
Cornstarch is a starch powder derived from the endosperm of corn kernels. It is a common food ingredient used to thicken liquids, like soups, sauces, and gravies. Unlike agar, which creates a firm gel, cornstarch thickens by causing the starches to swell and form a viscous solution when heated. This process is called gelatinization, and it results in a smooth, slightly opaque mixture.
Thickening Properties and Textures
The most significant difference between these two ingredients lies in their thickening mechanics and the resulting texture.
Agar Agar's Distinct Gelling
- Setting: Agar needs to be dissolved in a liquid and brought to a boil for its gelling properties to activate. It sets as the mixture cools, often solidifying at room temperature.
- Firmness: It creates a very firm, sturdy, and sometimes slightly brittle or rubbery gel that holds its shape well. This makes it perfect for molded desserts, firm jellies, or layered cakes.
- Heat Stability: Agar gel remains stable even at higher temperatures, unlike gelatin which melts. This property is a significant advantage for certain applications.
- Acidity: High-acidic foods, like citrus fruits, can inhibit agar's gelling power, and you may need to use more agar to compensate.
Cornstarch's Smooth Viscosity
- Setting: Cornstarch requires a hot liquid to thicken, and typically needs to be made into a 'slurry' with a cold liquid first to prevent clumping. Continued boiling can break down the thickening molecules, causing the liquid to thin again.
- Texture: It produces a smooth, creamy, and somewhat translucent texture, ideal for custards, puddings, and gravies. In certain applications, like some berry pies, it can lead to a slightly cloudy or murky appearance.
- Reversibility: Cornstarch thickeners are not as stable over time as agar gels, and can sometimes 'weep' or thin out.
Nutritional Profile: Agar Agar vs. Cornstarch
For those concerned with health and diet, the nutritional differences are notable.
- Agar Agar: This red algae extract is remarkably low in calories, fat, and sugar. It is primarily composed of dietary fiber, which aids digestion and can promote a feeling of fullness. As a plant-based product, it's suitable for vegan, vegetarian, and keto diets.
- Cornstarch: As a pure starch, it is a source of carbohydrates and contains more calories than agar. It offers little to no dietary fiber and is essentially a simple carb source, though it is naturally gluten-free. For individuals with certain metabolic conditions, cornstarch can be used to provide glucose.
Culinary Applications: When to Use Which
Choosing between agar agar and cornstarch depends entirely on the desired texture and type of dish.
Agar Agar is Best For:
- Firm Desserts: Making vegan jellies, gummies, and molded panna cotta that hold their shape at room temperature.
- Layered Cakes: Creating firm jelly layers in layered desserts, like the Japanese dessert anmitsu.
- Thickening Liquids: Soups and ice creams, where a stabilizing or thickening effect is needed, especially in vegan versions.
Cornstarch is Best For:
- Creamy Puddings and Custards: Its ability to create a smooth, creamy consistency without a rubbery texture is perfect for traditional puddings.
- Sauces and Gravies: Thickening sauces and gravies for savory dishes, where a smooth, glossy finish is desired.
- Pie Fillings: Providing a thick, stable filling for fruit pies, though it can sometimes be affected by acidic fruits.
- Crispy Coatings: Creating a light, crispy texture when used for dredging and deep-frying meats.
Comparison Table
| Feature | Agar Agar | Cornstarch | 
|---|---|---|
| Source | Red algae (seaweed) | Endosperm of corn kernels | 
| Thickening Style | Forms a firm, solid gel | Creates a creamy, viscous liquid | 
| Texture | Firm, brittle, potentially rubbery | Smooth, creamy, potentially slightly opaque | 
| Requires Heat | Must be dissolved and boiled to activate | Needs to be heated in liquid to thicken | 
| Temperature Stability | Very stable at room temperature and higher | Breaks down with prolonged boiling, less stable | 
| Vegan/Vegetarian | Yes, excellent vegan gelatin substitute | Yes, but offers different properties | 
| Nutrition | High in fiber, low-calorie, no sugar | Starch-based carbohydrate, caloric | 
Key Takeaways for Your Kitchen
- Agar for Firm Gels: Use agar agar when you need a very firm, heat-stable gel, especially for vegan jellies or molded desserts that must hold their shape at room temperature.
- Cornstarch for Creamy Viscosity: Opt for cornstarch when you want a smooth, creamy thickness for sauces, gravies, or traditional puddings.
- Consider Texture: Think about the desired final texture. Agar is firm and almost brittle, while cornstarch is soft and creamy. This is the most important factor in your choice.
- Note Acidity: Be mindful of acidic ingredients when using agar, as they can weaken its gelling power.
- Respect the Slurry: Always create a cornstarch slurry with cold liquid before adding it to hot mixtures to avoid lumps.
- Factor in Health: If you are aiming for a lower-calorie, high-fiber option, agar is the clear winner.
- Remember the Boil: Agar must be boiled to activate, while cornstarch thickens without needing to reach a full, rolling boil for activation.
Conclusion
While both agar agar and cornstarch function as thickening agents, they are not directly interchangeable, and the choice between them should be guided by your recipe's specific requirements. Agar, with its potent gelling power and heat stability, is the superior choice for firm, vegan gels and molded desserts. Cornstarch excels at producing smooth, creamy sauces, gravies, and puddings. By understanding their unique properties—agar's firm set and heat stability versus cornstarch's creamy, reversible thickening—you can confidently select the right ingredient for the perfect culinary result.
For further reading on the potential health benefits of agar, including its effects on cholesterol management and weight control, you can explore research from the National Institutes of Health.