The Environmental Cycle of Methylmercury
Methylmercury is an organic and highly toxic form of mercury, a naturally occurring element found in the earth's crust. It enters the environment through both natural phenomena and human activity. Natural sources include volcanic eruptions and forest fires, while human activities are primarily responsible for the majority of new mercury entering the ecosystem, particularly from the burning of coal and other fossil fuels. This inorganic mercury is released into the atmosphere and eventually settles into bodies of water and soil through rain and dust.
Once in an aquatic environment, microorganisms play a crucial role in transforming inorganic mercury into the much more hazardous methylmercury. This process primarily occurs in low-oxygen (anaerobic) sediments of lakes, rivers, and oceans, where specific types of bacteria convert the mercury.
Bioaccumulation and Biomagnification in the Food Chain
From these sediments, the methylmercury begins its ascent up the food chain through two important processes: bioaccumulation and biomagnification.
- Bioaccumulation: This is the buildup of a substance, such as methylmercury, in an organism's tissues over its lifetime. Fish absorb methylmercury from the water passing over their gills and from the food they consume. Unlike many other substances, methylmercury is not easily eliminated from the body and instead accumulates, primarily in the muscle tissue.
- Biomagnification: This is the increase in concentration of a substance as it moves up the food chain. When a small predatory fish eats many smaller, contaminated organisms, the predator accumulates all the methylmercury from its prey. This process is repeated at each trophic level, meaning large, long-lived predatory fish at the top of the food chain accumulate the highest concentrations of methylmercury. Human exposure is predominantly through the consumption of these contaminated fish and seafood.
Identifying Dietary Sources of Methylmercury
While methylmercury is found in trace amounts in nearly all fish, the concentration varies significantly by species. The FDA and EPA provide guidance to help consumers, particularly vulnerable populations, make informed choices to minimize exposure.
High-Mercury Fish to Limit or Avoid
Larger, longer-lived, and predatory fish tend to have the highest concentrations of methylmercury due to biomagnification. These include:
- Shark
- Swordfish
- King Mackerel
- Bigeye Tuna
- Tilefish (especially from the Gulf of Mexico)
- Orange Roughy
- Marlin
Lower-Mercury Fish to Enjoy More Often
Smaller and shorter-lived fish and shellfish typically have much lower levels of methylmercury. These include:
- Salmon (Wild and Alaska)
- Shrimp
- Canned Light Tuna
- Catfish
- Scallops
- Oysters
- Sardines
Comparison Table: High vs. Low Mercury Seafood
| Seafood Type | Example Species | Methylmercury Level | Consumption Advice (Vulnerable Groups) | 
|---|---|---|---|
| Higher-Mercury | Shark, Swordfish, King Mackerel, Bigeye Tuna | High | Limit or Avoid | 
| Tilefish (Gulf of Mexico), Orange Roughy | High | Limit or Avoid | |
| Lower-Mercury | Salmon, Shrimp, Canned Light Tuna, Catfish | Low | 2-3 servings per week recommended | 
| Cod, Tilapia, Scallops, Oysters | Low | 2-3 servings per week recommended | 
Health Implications of Methylmercury Exposure
Methylmercury is particularly concerning because it is easily absorbed by the gastrointestinal tract and can pass through the blood-brain and placental barriers. This allows it to cause neurological damage, especially in the developing brains of fetuses and infants.
Potential health effects from high exposure can include:
- Neurological symptoms, such as loss of peripheral vision and coordination problems.
- Sensory disturbances, including tingling or 'pins and needles' feelings in the extremities.
- Impairment of speech, hearing, and walking.
- Cognitive impacts, including memory problems and attention deficits, especially in children exposed in utero.
- Cardiovascular issues, though evidence is still being studied.
For the general population, average consumption levels of most seafood pose little risk. The risk is highest for those who consume large quantities of high-mercury fish over time, leading to accumulation in the body.
How to Reduce Your Exposure to Methylmercury
Since cooking and other preparation methods cannot remove methylmercury from fish, the best way to minimize intake is by making smart choices at the grocery store or when dining out. Here are some strategies:
- Diversify your fish consumption: Don't rely on just one type of fish. Instead, choose from a wide variety of seafood, opting for more low-mercury choices.
- Follow official guidelines: Pregnant women, nursing mothers, and young children should adhere to fish consumption advisories issued by health authorities like the FDA and EPA.
- Choose smaller fish: Opt for fish lower on the food chain, such as sardines and canned light tuna, which have less time to accumulate mercury.
- Check local advisories: If you consume recreationally caught fish, check for local or state advisories, as mercury levels can be higher in certain local water bodies.
For authoritative information on fish consumption, refer to the FDA's advice about eating fish.
Conclusion
Yes, methylmercury is present in food, primarily in fish and shellfish, due to its bioaccumulation and biomagnification within aquatic food chains. While high levels pose neurological risks, particularly to the developing fetus and young children, most people's dietary exposure is well within safe limits, and the nutritional benefits of fish, such as omega-3 fatty acids, are significant. The key to safe fish consumption lies in moderation and making informed choices by favoring lower-mercury varieties. By understanding the source and accumulation process of methylmercury, consumers can confidently navigate their seafood choices to enjoy the health benefits while minimizing risk.