Fructans represent a versatile class of carbohydrates that are present in thousands of plant species and play a crucial role in the diet, particularly as a source of prebiotic fiber. Chemically, a fructan is a polymer of fructose molecules, but its classification as either an oligosaccharide or a polysaccharide depends entirely on its degree of polymerization, or chain length. This distinction is critical for understanding their function, digestion, and impact on human health.
Fructan as an Oligosaccharide
When fructans have a shorter chain length, typically containing 2 to 9 fructose units, they are classified as oligosaccharides. These are more specifically known as fructo-oligosaccharides (FOS). The 'O' in the acronym FODMAP (Fermentable Oligosaccharides, Disaccharides, Monosaccharides, and Polyols) refers to these oligosaccharides, including fructans.
- Fructo-oligosaccharides (FOS): FOS are composed of a few fructose molecules linked together, often with a glucose molecule at one end. They are common in a variety of foods, and due to their short chain length, they are highly fermentable by gut bacteria in the large intestine.
 - Prebiotic Function: As prebiotics, FOS serve as a food source for beneficial bacteria like Bifidobacteria and Lactobacillus in the gut, promoting a healthier microbial environment.
 
Fructan as a Polysaccharide
When the fructose chain of a fructan grows longer, typically with more than 10 units, it is classified as a polysaccharide. The most common example of a fructan polysaccharide is inulin. Inulin can have a degree of polymerization ranging from 10 to over 60 units, and its longer chains give it different physical properties compared to its shorter-chain counterparts.
- Inulin: Found abundantly in chicory root, Jerusalem artichoke, and garlic, inulin is widely used in the food industry as a functional ingredient. Its longer, heavier chains make it useful as a fat replacer or a bulking agent, adding texture to foods.
 - Digestion and Fermentation: Like FOS, inulin is not digestible by human enzymes and travels to the large intestine. However, due to its longer chain, it is fermented more slowly and throughout the length of the colon, providing sustained prebiotic benefits.
 
Types of Fructan Based on Structure
Beyond chain length, fructans are also categorized by the specific linkages between the fructose units and their overall structure. The primary types are:
- Inulin-type: These are characterized by linear chains of fructose units joined by $eta$-(2→1) linkages. They are found in plants like chicory and artichoke.
 - Levan-type: Found primarily in temperate grasses and produced by microorganisms, levans feature a predominance of $eta$-(2→6) linkages.
 - Graminan-type: These mixed-type fructans, common in wheat, rye, and barley, contain both $eta$-(2→1) and $eta$-(2→6) linkages, resulting in a more complex, branched structure.
 
Fructan Digestion and Its Effects on the Body
The human digestive system lacks the enzyme necessary to break the specific $eta$-linkages that hold fructan molecules together. For this reason, fructans pass undigested into the large intestine. This malabsorption is what allows them to act as prebiotics, as they are consumed by gut microbiota. For most people, this process is normal and beneficial. However, in individuals with conditions like Irritable Bowel Syndrome (IBS), the fermentation process can cause unpleasant gastrointestinal symptoms due to an extra-sensitive gut. The fermentation produces gases like hydrogen, leading to bloating, flatulence, and abdominal discomfort. This has led to the development of the low-FODMAP diet, which restricts fructan intake to manage symptoms.
Fructan vs. Other Carbohydrates
To better understand fructan, it's useful to compare it with other common carbohydrates. Fructan's unique structure and indigestibility set it apart from simple sugars and other starches.
| Feature | Fructan | Simple Sugars (Monosaccharides) | Starch (Polysaccharide) | 
|---|---|---|---|
| Saccharide Type | Oligosaccharide and Polysaccharide | Monosaccharide | Polysaccharide | 
| Composed Of | Fructose units (and often a terminal glucose) | Single sugar unit (e.g., glucose, fructose) | Glucose units | 
| Digestion by Humans | Poorly digested; Fermented in the large intestine | Easily and fully digested in the small intestine | Broken down into glucose in the small intestine | 
| Bonding | Primarily β-fructosyl linkages | None (single unit) | α-glycosidic linkages | 
| Example | Inulin, FOS | Fructose, Glucose | Amylose, Amylopectin | 
| Function in Body | Prebiotic fiber, promotes gut health | Quick energy source | Energy storage | 
Sources of Fructan in Food
Fructans are naturally present in a wide range of everyday foods. Some of the most common sources include:
- Vegetables: Onions, garlic, leeks, artichokes, and asparagus.
 - Grains: Wheat, barley, and rye.
 - Fruits: Ripe bananas and watermelon.
 - Legumes and Nuts: Red kidney beans, cashews, and pistachios.
 - Additives: Inulin, a type of fructan, is often added to processed foods like yogurt, cereal bars, and fiber supplements for its prebiotic properties.
 
Conclusion
Fructan is a complex saccharide that encompasses both oligosaccharide and polysaccharide forms, most notably as fructo-oligosaccharides (FOS) and inulin. Its indigestible nature is a key feature, allowing it to function as a prebiotic fiber that feeds beneficial gut bacteria. While this provides significant health benefits for many, for individuals with certain sensitivities, the bacterial fermentation of fructans can lead to uncomfortable digestive symptoms. By understanding what kind of saccharide fructan is, consumers can make more informed dietary choices, managing their intake for better gut health. For further reading, more on fructan research can be found on reliable health resource websites like the National Institutes of Health.
What kind of saccharide is fructan?: Keypoints
- Fructans are complex carbohydrates: They are polymers of fructose molecules that can be either oligosaccharides (short chains) or polysaccharides (long chains).
 - Two main types based on length: Shorter-chain fructans (2-9 units) are called fructo-oligosaccharides (FOS), while longer-chain versions (>10 units) are known as inulin.
 - Human body cannot digest them: Due to the specific $eta$-glycosidic linkages, humans lack the enzymes to break down fructans in the small intestine.
 - Function as prebiotics: As they reach the large intestine undigested, fructans are fermented by gut bacteria, providing health-promoting prebiotic benefits.
 - Common trigger for IBS symptoms: For sensitive individuals, the fermentation of fructans can lead to gas, bloating, and other digestive discomforts, making it a key focus of the low-FODMAP diet.
 - Found in many common foods: Important dietary sources include wheat, onions, garlic, and chicory root.