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Demystifying Almonds: What are the bad chemicals in almonds?

5 min read

While revered for their health benefits, almonds, particularly the bitter variety, contain the toxic compound amygdalin, which breaks down into hydrogen cyanide when ingested. This naturally leads many to question: what are the bad chemicals in almonds, and are the sweet, commercially sold nuts safe for consumption?

Quick Summary

This guide details the potential negative compounds in almonds, including the toxins in bitter almonds, antinutrients like phytic acid and oxalates, mycotoxins, allergens, and residues from processing. It helps distinguish between safe sweet almonds and toxic bitter ones.

Key Points

  • Bitter vs. Sweet: Raw bitter almonds contain amygdalin, which releases deadly cyanide upon digestion, while the sweet almonds commonly sold in stores are safe.

  • Antinutrients: Phytic acid and oxalates in almonds can hinder mineral absorption and increase kidney stone risk, particularly with excessive intake.

  • Mold and Mycotoxins: Improperly stored or damaged almonds can harbor mold that produces carcinogenic aflatoxins, a major food safety concern.

  • Processing Residues: US-sold almonds are pasteurized to kill bacteria, which can involve steam or a chemical called propylene oxide (PPO), though residues are minimal.

  • Allergenic Potential: Almonds contain proteins that are common allergens, and reactions can be severe for sensitive individuals.

  • Moderation is Essential: Due to their high fat and calorie content, and presence of compounds like oxalates, excessive almond consumption can cause weight gain and digestive issues.

  • Preparation Matters: Soaking or roasting can help reduce certain compounds like antinutrients and tannins, although effects vary and may also alter nutrient profiles.

In This Article

Almonds are a nutrient-dense food, providing healthy fats, protein, and a host of vitamins and minerals like vitamin E and magnesium. However, as with many natural foods, they contain certain compounds that can be harmful in specific situations or quantities. Understanding these chemicals is key to incorporating almonds safely into a balanced diet.

Amygdalin and the Danger of Bitter Almonds

The most serious chemical risk associated with almonds comes from a compound called amygdalin. This cyanogenic glycoside is responsible for the characteristic bitter taste found in certain varieties of the almond tree (Prunus dulcis var. amara).

When bitter almonds are ingested, the body’s enzymes hydrolyze the amygdalin, releasing highly toxic hydrogen cyanide (HCN). As few as 6 to 10 raw bitter almonds can cause severe poisoning in an adult, and 50 or more can be lethal. The danger is so significant that raw bitter almonds are not sold commercially in the United States, and imported products are strictly regulated.

It is crucial to distinguish bitter almonds from the sweet variety (Prunus dulcis var. dulcis), which are the kind found in grocery stores. Sweet almonds contain only trace, non-toxic levels of amygdalin due to a genetic mutation, making them safe to eat. This is why they are so widely consumed without issue.

Antinutrients: Phytic Acid and Oxalates

Antinutrients are plant compounds that can interfere with the absorption of other nutrients. While not inherently bad and often offering their own health benefits, they can become a concern with excessive consumption, especially for those with mineral deficiencies or specific health conditions.

Phytic Acid (Phytates)

  • Mineral Binding: Phytic acid binds to essential minerals like calcium, zinc, and iron in the digestive tract, which can reduce their absorption. This effect is most pronounced when consuming high-phytate foods with mineral-rich meals.
  • Mitigation: Soaking and roasting almonds can help reduce phytate levels, potentially improving mineral bioavailability, though the research is mixed on its effectiveness in nuts.

Oxalates

  • Kidney Stones: Almonds are naturally high in oxalates. In some individuals, particularly those predisposed to kidney stones, excessive intake of oxalates can increase the risk of forming calcium oxalate crystals.
  • Moderation: For those with a history of kidney stones, consuming almonds in moderation and staying hydrated is advisable to prevent an excessive build-up of oxalates.

Mycotoxins from Mold Contamination

Mycotoxins are toxic chemicals produced by certain molds that can contaminate crops, including almonds, during harvest or storage.

Aflatoxins

  • Carcinogenic Risk: Aflatoxins, produced by molds like Aspergillus flavus, are a major food safety concern. They are potent carcinogens that can affect the liver.
  • Prevention and Regulation: Regulatory bodies worldwide impose strict limits on aflatoxin levels. The almond industry implements rigorous practices, such as winter sanitation and controlled storage conditions, to prevent contamination. Consumers should inspect nuts for signs of mold or discoloration and discard them.

Commercial Processing and Added Substances

For safety, commercially sold almonds are subject to processing, which can introduce some chemicals, though generally at levels deemed safe by regulatory bodies.

  • Pesticide Residues: Conventional almond farming, like many agricultural practices, uses pesticides. For those concerned, organic almonds are grown without these chemicals.
  • Propylene Oxide (PPO): All US-sold almonds are pasteurized to prevent bacterial contamination, such as Salmonella. One approved method is treatment with propylene oxide (PPO), a substance classified as 'possibly carcinogenic to humans' but which dissipates after treatment. Alternatively, steam pasteurization is used and preferred by many consumers.

The Challenge of Almond Allergens

Almonds are a common tree nut allergen and a significant cause of food-related anaphylaxis alongside peanuts.

  • Immune Response: An almond allergy is an immune system reaction to specific proteins in the nut, triggering symptoms that can range from mild oral irritation to severe, life-threatening anaphylaxis.
  • Cross-Reactivity: Cross-reactivity with other tree nuts and pollens is common. For example, individuals with a birch pollen allergy may experience oral allergy syndrome from almonds. Strict dietary avoidance is necessary for those with a confirmed allergy.

Comparing Almond Preparations and Their Chemicals

The method of preparation can influence the chemical composition of almonds. The following table compares raw, soaked, and roasted almonds.

Feature Raw Almonds Soaked Almonds Roasted Almonds
Antinutrients (Phytic Acid) Present; can inhibit mineral absorption Slightly reduced, but research is mixed on the significance Generally reduced due to heat
Texture Hard and crunchy Softer, less bitter due to tannin reduction Crispier texture with a deeper flavor
Nutrient Content Intact nutrients; potentially lower mineral absorption Potentially improved fat absorption; mixed effects on mineral absorption Some heat-sensitive antioxidants and vitamins may be reduced
Allergens Contains allergens; can trigger reactions in sensitized individuals Contains allergens; soaking does not eliminate the risk Most major allergens, like amandin, are heat-stable and remain
Acrylamide Not present Not present Forms during roasting, but can be minimized with low-temperature roasting
Digestibility May be harder to digest for some individuals Softens, potentially easier to digest Easier for some people to digest than raw

How to Reduce 'Bad' Compounds in Almonds

To maximize the health benefits of almonds while minimizing potential downsides, consider these preparation tips:

  • Distinguish Varieties: Ensure you are purchasing and consuming sweet almonds. All commercially sold almonds in the US are safe, pasteurized varieties.
  • Soak Almonds: If you experience digestive issues, soaking almonds for 8-12 hours can reduce the bitterness from tannins and may slightly reduce antinutrient levels.
  • Practice Good Storage: Always store almonds in a cool, dry place to prevent the growth of mold and the development of aflatoxins. Discard any almonds that look discolored or shriveled.
  • Opt for Organic: Choosing organic almonds can reduce exposure to conventional pesticide residues.
  • Control Roasting: If you prefer roasted almonds, consider roasting them at home at lower temperatures (around 140°C) for a shorter time to minimize the formation of acrylamide.
  • Vary Your Diet: The risks of mineral malabsorption from antinutrients are largely offset by a varied diet. Rotating your intake of nuts and other whole foods ensures a wide range of nutrients and prevents over-reliance on a single source.

Conclusion: Moderation and Awareness is Key

While it is important to be aware of the potentially harmful chemicals in almonds, such as the amygdalin in bitter varieties and the antinutrients in sweet varieties, the commercially available sweet almonds are safe for the vast majority of the population. The key is moderation and informed consumption. By buying from reputable sources, practicing proper storage, and being mindful of preparation methods, you can confidently enjoy the numerous health benefits almonds offer without undue worry. For those with allergies or specific medical conditions, consulting a healthcare professional is always the best course of action.

Additional Resource

For further information on food safety and processing standards for almonds, you may wish to visit the Almond Board of California's website.

Frequently Asked Questions

No, sweet almonds are not poisonous. They contain only trace amounts of the toxin amygdalin, which is not enough to cause poisoning.

Bitter almonds have a distinctly sharp, bitter taste due to their high amygdalin content, while sweet almonds have a mild, nutty flavor. In the US, raw bitter almonds are not sold commercially, so you don't need to worry about accidentally purchasing them at the grocery store.

While some claim that soaking reduces phytic acid, research on almonds specifically shows only a minimal reduction (less than 5%) after prolonged soaking. The effects of soaking on antinutrient levels are mixed.

Yes, for individuals prone to kidney stones, consuming too many almonds can contribute to their formation because almonds are high in oxalates, which can form crystals with calcium.

Aflatoxins are carcinogenic mycotoxins produced by mold on almonds if they are improperly stored or damaged. To minimize risk, purchase almonds from reputable sellers and discard any that appear moldy or discolored.

Yes, almonds are calorie-dense, and eating too many can contribute to weight gain if not accounted for in your overall caloric intake. A standard serving is about one ounce (23 kernels).

Yes, the skin of sweet almonds is safe and contains beneficial fiber and antioxidants, though it also contains tannins and lectins. For those with digestive sensitivities, removing the skin after soaking may help.

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Medical Disclaimer

This content is for informational purposes only and should not replace professional medical advice.