Understanding Alkaline Water's Instability
Unlike standard purified water, alkaline water, especially ionized water, is inherently unstable. Its primary value—the elevated pH and negative oxidation-reduction potential (ORP)—is temporary and highly susceptible to environmental factors. The moment it is produced or opened, alkaline water begins to interact with its surroundings, particularly oxygen and light. This interaction causes the ORP to drop and the pH to slowly return toward a neutral state. When stored improperly, this process accelerates, rapidly diminishing the water's supposed health benefits. Storing it in plastic bottles introduces additional variables that can impact both water quality and safety.
The Problem with Storing Water in Plastic
Plastic containers are not inert. Over time and when exposed to heat or sunlight, plastic can leach chemicals into the water it contains. For single-use polyethylene terephthalate (PET) bottles, common chemicals like antimony can be released, while reusable plastics might contain compounds like BPA (though many are now labeled 'BPA-free') or other plasticizers. Heat significantly accelerates this leaching process, which can negatively affect both the water's taste and its chemical composition. While alkaline water is not chemically aggressive enough to cause rapid degradation, the long-term interaction, especially under poor storage conditions, is a notable concern. Furthermore, microplastics, tiny particles of degraded plastic, have been found in most bottled water brands, adding another layer of contamination risk. The porous nature of plastic can also allow vapors from surrounding chemicals (like gasoline or cleaning products) to permeate the container and taint the water.
Short-Term vs. Long-Term Plastic Storage
For short-term storage, such as for a day at work or during exercise, a BPA-free plastic bottle stored in a cool place is generally acceptable. The risks of chemical leaching and degradation of the water's alkaline properties are minimal within a 24-hour window. However, relying on plastic for long-term storage is not advisable for several reasons. Beyond the 48-72 hour mark, the quality of the alkaline water will have likely decreased significantly, and the risk of plastic-related issues increases substantially. The best practice for home-based alkaline water systems is to consume the water as fresh as possible, or to use superior storage materials if it must be kept for later.
Best Practices for Maximizing Alkaline Water Longevity
To preserve the properties of alkaline water, a few key strategies are essential:
- Choose the right container: Opt for airtight glass mason jars or vacuum-sealed stainless steel bottles. Glass is inert and prevents any leaching, while stainless steel offers durability and complete light blockage.
- Limit air exposure: Fill the container to the very top, leaving minimal air space. Oxygen exposure is a primary factor in the degradation of the water's ORP.
- Control temperature: Store the water in a cool, dark place, ideally in a refrigerator. Heat and light are catalysts for chemical changes and can degrade both the water and the plastic container.
- Avoid certain materials: Never store alkaline water in metal containers that are not stainless steel, as some metals can react with the water and alter its properties. Avoid reusing thin, single-use plastic bottles, which are more prone to degradation and chemical release over time.
- Store away from chemicals: Keep all water containers, regardless of material, away from cleaning supplies, gasoline, or other strong chemicals whose vapors could permeate the plastic.
Comparison of Storage Containers for Alkaline Water
| Feature | Plastic Bottles (Single-Use PET) | Plastic Bottles (BPA-Free) | Glass Bottles | Stainless Steel (Vacuum-Sealed) | 
|---|---|---|---|---|
| Recommended Storage Time | 24 hours (best) | Up to 72 hours | Up to 1 week | Up to 1 week | 
| Effect on pH & ORP | Rapid degradation | Moderate degradation | Slowest degradation | Slowest degradation | 
| Chemical Leaching Risk | High, especially with heat | Low to Moderate (depends on plastic) | None | None | 
| Protection from Light | Poor | Poor (often clear) | Poor (often clear) | Excellent (opaque) | 
| Durability & Reusability | None | Good | Excellent | Excellent | 
| Cost | Very low | Low to Moderate | Moderate | High | 
| Best For | On-the-go, immediate consumption | Daily use, short transport | Refrigerator storage | Long-term home or office use | 
The Risks of Improper Plastic Storage
Beyond the loss of alkaline properties, improper storage of water in plastic bottles poses several risks. Exposure to heat and sunlight not only encourages chemical leaching but also promotes bacterial growth within the bottle, especially if it is reused and not properly cleaned. The scuffs and scratches that develop on reused plastic provide perfect breeding grounds for harmful bacteria. While bottled water is generally safe to drink long past its printed date, this applies to unopened, standard bottled water and assumes proper storage away from heat and light. For delicate alkaline water, these conditions are more critical, and its intended benefits will be lost long before any microbial contamination becomes an issue. For those who prioritize health and purity, understanding these risks is essential for making informed hydration choices. The best course of action is to reserve plastic containers for the shortest possible storage periods and to switch to glass or stainless steel for anything longer than a day.
Conclusion: Prioritize Short-Term Use in Plastic
Ultimately, the duration you can store alkaline water in plastic bottles is quite limited if you want to preserve its intended properties. While the water remains potable for longer periods under proper conditions, its elevated pH and antioxidant potential begin to degrade noticeably within 48 to 72 hours. The potential for chemical leaching, especially when exposed to heat or sunlight, further reduces the desirability of plastic for long-term storage. To get the full benefits of alkaline water, consume it as soon as possible after producing or opening it. For any storage need beyond a day, transitioning to glass or vacuum-sealed stainless steel is the recommended best practice for maintaining both the water's quality and your peace of mind. For more information on safely storing emergency water supplies, see the guidelines from Ready.gov on Storing Water.