The Truth About Copper's Reactivity
Copper's primary safety concern stems from its reactivity with acidic foods and liquids, such as vinegar, lemon juice, wine, and tomato products. When acidic substances come into contact with bare, unlined copper, a chemical reaction can occur. This reaction can cause copper salts to leach into the food, which can be toxic if ingested in large quantities. Symptoms of copper toxicity can include nausea, vomiting, diarrhea, and abdominal pain.
For this reason, reputable modern manufacturers line their copper cookware and measuring cups with a non-reactive metal, typically stainless steel or tin. This food-safe lining acts as a protective barrier, preventing the copper from coming into direct contact with ingredients and eliminating the risk of copper leaching.
Lined vs. Unlined: The Crucial Distinction
Not all copper measuring cups are created equal. The key factor is whether the interior surface is bare copper or protected by a food-grade lining.
Benefits of Lined Copper Measuring Cups
- Safe for all ingredients: The protective barrier allows for safe measurement of all types of ingredients, including highly acidic ones.
- Durable: Stainless steel-lined copper cups are highly durable and resistant to scratches and corrosion.
- Aesthetic appeal: They still provide the classic, elegant look of copper on the exterior.
- Hygienic: Copper has natural antimicrobial properties, which, combined with the non-reactive lining, makes them a hygienic choice.
Risks of Unlined Copper Measuring Cups
- Chemical reaction: Acidic foods can react with the copper, potentially contaminating ingredients.
- Metallic taste: Leaching copper can impart an unpleasant metallic taste to food and liquids.
- High maintenance: Unlined copper requires more careful, delicate cleaning to prevent tarnish and corrosion, and is not dishwasher safe.
- Limited use: They can only be safely used with non-acidic or dry ingredients.
How to Care for Copper Measuring Cups
Proper maintenance is essential to ensure the safety and longevity of your copper measuring cups, especially those that are lined.
- Hand wash only: Never place copper measuring cups in the dishwasher, as the harsh detergents and high temperatures can damage the finish and potentially compromise the interior lining.
- Clean immediately: Wash the cups with warm, soapy water and a soft sponge immediately after each use.
- Dry thoroughly: After washing, dry the cups completely with a soft cloth to prevent water spots and tarnish.
- Regular polishing: For a shiny finish, polish the exterior occasionally with a copper-specific cleaner or a homemade paste of lemon and salt.
Comparison Table: Copper vs. Other Materials
| Feature | Lined Copper | Stainless Steel | Glass | Plastic | 
|---|---|---|---|---|
| Safety (Acidic Foods) | Safe | Safe | Safe | Safe (BPA-free) | 
| Durability | High | Very High | Medium (breakable) | Low (can crack) | 
| Aesthetic Appeal | High | Medium | Medium | Low | 
| Dishwasher Safe? | No | Yes (usually) | Yes | Yes (usually) | 
| Liquid Measurements | Good | Good | Excellent (with spouts) | Good (with spouts) | 
| Dry Measurements | Excellent | Excellent | Poor (can cause parallax error) | Fair (lightweight) | 
| Heat Reactive? | No (due to lining) | No | No | Yes (melts/warps) | 
| Tarnishes/Patina | Yes (exterior) | No | No | No | 
Identifying Quality and Safety
When purchasing copper measuring cups, prioritize safety by checking the product description and customer reviews to ensure the set is properly lined. Look for clear indications that the interior is made of a food-safe metal, such as stainless steel. This is more critical than a thick exterior copper coating, as the barrier prevents any reaction with your ingredients.
For those interested in the historical and practical uses of unlined copper, it is traditionally used for non-reactive purposes. For example, unlined copper bowls are excellent for whisking egg whites because the copper ions form stable bonds with the egg proteins, resulting in a more voluminous and stable foam. However, for general cooking and measuring tasks, especially with liquids, lined measuring cups are the safe and practical choice.
Conclusion
Using copper measuring cups is perfectly safe, provided you choose products that are lined with a non-reactive, food-grade material like stainless steel. The risk of copper toxicity only arises when acidic foods come into contact with unlined copper surfaces, which is not an issue with modern, properly constructed sets. By selecting a lined set and following proper hand-washing and drying procedures, you can enjoy the classic elegance and durability of copper in your kitchen without any health concerns.
Health Note
While copper is a necessary nutrient, and exposure from lined cookware is minimal, those with certain rare genetic conditions, such as Wilson's disease, which causes the body to retain excess copper, should consult a doctor regarding any copper exposure. For the general population, the trace amounts from incidental contact with tarnished exterior surfaces are not a cause for concern.
Sources
National Institutes of Health Centers for Disease Control and Prevention | CDC Advanced Mixology