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What is a calcium supplement made of?

4 min read

According to a 2011-12 survey, over half of adult Australians and many in the US consume inadequate levels of calcium from food sources, making supplements a popular option. However, not all supplements are created equal, as their composition varies based on the form of calcium used and other additives, which affects absorption, cost, and effectiveness.

Quick Summary

Calcium supplements are primarily composed of different calcium compounds, such as carbonate or citrate, sourced from minerals or plants, and often include other ingredients like vitamin D.

Key Points

  • Diverse Compounds: The primary ingredient in a calcium supplement is elemental calcium combined with another compound, most commonly carbonate or citrate.

  • Carbonate vs. Citrate: Calcium carbonate offers a higher percentage of elemental calcium and is less expensive, but it needs stomach acid for absorption. Calcium citrate is better absorbed, especially on an empty stomach or by those with low stomach acid, but it is more expensive.

  • Role of Vitamin D: Many supplements include vitamin D, which is a crucial cofactor that significantly improves the body's ability to absorb calcium.

  • Natural Sources: Raw calcium materials can be sourced from minerals like limestone and chalk (for carbonate), or synthetically produced (for citrate).

  • Manufacturing Process: Supplements are manufactured through a process of blending, granulating, and compressing the active ingredients and fillers into their final form.

  • Digestive Comfort: For people prone to digestive issues like gas or constipation, calcium citrate is often the more tolerable choice.

In This Article

The Primary Forms of Calcium in Supplements

At its core, a calcium supplement provides calcium, a mineral vital for bone density, nerve function, and muscle contraction. However, elemental calcium—the pure calcium available for absorption—is always bound to another compound. The type of compound determines the supplement's properties, including its elemental calcium concentration and how well the body absorbs it. The two most common forms are calcium carbonate and calcium citrate, but other versions also exist to address specific needs.

Calcium Carbonate: High Concentration, Lower Cost

Calcium carbonate is the most widely available and cost-effective form of calcium supplement. Its high elemental calcium content, at approximately 40% by weight, means you need fewer tablets to meet your daily requirements. This compound is typically sourced from naturally occurring minerals like limestone, chalk, and marble, or from fossilized oyster shells and corals.

  • Absorption: This form requires stomach acid for proper absorption. Therefore, it is best to take calcium carbonate supplements with a meal to enhance bioavailability.
  • Side Effects: Some individuals, particularly older adults, may experience gastrointestinal side effects such as gas, bloating, and constipation. These effects can often be minimized by taking smaller, more frequent doses with meals.
  • Antacid Properties: Because it neutralizes stomach acid, calcium carbonate is the active ingredient in many over-the-counter antacid products.

Calcium Citrate: Easy Absorption, Better Tolerance

Calcium citrate is a more expensive alternative to calcium carbonate but is also more easily absorbed by the body. Unlike calcium carbonate, it does not require stomach acid for absorption, making it an ideal choice for people with low stomach acid (achlorhydria), those over 50, or individuals taking medications that reduce stomach acid, such as proton pump inhibitors.

  • Elemental Calcium: Calcium citrate contains only about 21% elemental calcium by weight. As a result, you may need to take more tablets to get the same dosage as calcium carbonate.
  • Versatility: It can be taken at any time, with or without food, offering greater convenience.
  • Fewer Side Effects: It is less likely to cause constipation, gas, or bloating compared to its carbonate counterpart, making it a better choice for those with sensitive stomachs.
  • Sourcing: Calcium citrate is the calcium salt of citric acid and is produced synthetically.

Other Forms and Ingredients

Besides the main two, several other calcium compounds are used in supplements, though less commonly due to their lower elemental calcium content or higher cost. These include:

  • Calcium Lactate (13% elemental calcium): Can be absorbed at various pH levels and is gentler on the digestive system.
  • Calcium Gluconate (9% elemental calcium): Less concentrated, often used for medical purposes rather than daily supplementation.
  • Calcium Phosphate: Naturally found in animal bones and milk, it provides both calcium and phosphorus, but can be more expensive.

Crucially, many calcium supplements contain more than just calcium. Vitamin D is often added because it is essential for the intestinal absorption of calcium. Other ingredients may include magnesium to support bone mineralization, fillers, binders to hold tablets together, and flavorings. Some newer products use plant-based calcium derived from marine algae, which can offer additional trace minerals.

Comparison Table: Calcium Carbonate vs. Calcium Citrate

Feature Calcium Carbonate Calcium Citrate
Elemental Calcium 40% (high concentration) 21% (lower concentration)
Cost Less expensive More expensive
Absorption Requires stomach acid; best taken with food Does not require stomach acid; can be taken anytime
Digestive Issues Can cause gas, bloating, and constipation Less likely to cause digestive side effects
Best For Individuals with normal stomach acid and sensitive to cost People with low stomach acid, older adults, or those on acid-reducing medication

The Supplement Manufacturing Process

The manufacturing of calcium supplements involves several key stages to transform raw ingredients into the final product. The process often begins by sourcing the raw calcium compound, such as mining limestone for calcium carbonate. The compound is then purified and milled into a fine powder.

  1. Blending: The calcium powder is blended with other ingredients, like vitamin D, binders, and fillers, to ensure a uniform mixture.
  2. Granulation: This process binds the powdered ingredients together into larger granules, which prevents segregation and helps with the compression of tablets.
  3. Compression: The granules are then compressed into their final form, whether a tablet, capsule, or chewable.
  4. Coating: Many tablets receive a coating for ease of swallowing, improved taste, or to protect the active ingredients.
  5. Packaging: The finished supplements are packaged and sealed for distribution.

How to Choose the Right Supplement

Selecting the best calcium supplement depends on several factors, including your health status, diet, and budget. For most people with adequate stomach acid, calcium carbonate is an effective and economical option. However, if you are over 50, have had bariatric surgery, or use acid-reducing medications, the higher absorption of calcium citrate may be a better investment. Always check the supplement facts label to confirm the amount of elemental calcium and presence of other beneficial nutrients like vitamin D. Before starting any new supplement, it is wise to consult with a healthcare professional to ensure it is the right choice for your individual needs and to discuss potential interactions with other medications. A good resource for further research is the National Institutes of Health Fact Sheet on Calcium.

Conclusion

Calcium supplements are not one-size-fits-all, with their composition dictating their absorption, cost, and potential side effects. The majority are made with either calcium carbonate or calcium citrate, each offering distinct advantages. Carbonate is more concentrated and budget-friendly but requires stomach acid and can cause digestive upset. Citrate, while more expensive and less concentrated, is easier to absorb and gentler on the stomach. Additional ingredients, particularly vitamin D, are often included to maximize effectiveness. Understanding these different formulations is key to making an informed choice that best supports your bone health and overall well-being.

Frequently Asked Questions

The primary difference lies in their absorption properties and elemental calcium content. Calcium carbonate has a higher elemental calcium concentration but requires stomach acid for absorption, while calcium citrate is more easily absorbed, even on an empty stomach, but contains less elemental calcium per dose.

The calcium can come from various sources. Calcium carbonate is often derived from minerals like limestone, chalk, or oyster shells, while calcium citrate is a synthetic calcium salt.

Vitamin D is included in many calcium supplements because it is vital for helping the body effectively absorb calcium from the digestive tract into the bloodstream.

Yes, some people experience gastrointestinal side effects like gas, bloating, or constipation, particularly with calcium carbonate. Calcium citrate is generally less likely to cause these issues.

For those with low stomach acid, calcium citrate is the better option because it does not depend on stomach acid for absorption. This is especially relevant for older adults or those on acid-reducing medications.

Elemental calcium is the actual amount of pure calcium that is available for your body to absorb from a supplement. This figure is listed on the 'Supplement Facts' panel of the product.

The manufacturing process involves several steps, including sourcing and processing the raw calcium, blending it with other ingredients like binders and vitamins, granulating the mixture, and finally compressing it into a tablet or capsule.

References

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Medical Disclaimer

This content is for informational purposes only and should not replace professional medical advice.