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What is the pH of black coffee and milk?

4 min read

According to a 2018 study in Scientific Reports, the pH of black coffee typically falls between 4.85 and 5.4, making it mildly acidic. When you add milk, its naturally higher pH level helps to neutralize the coffee's acidity, resulting in a less acidic final beverage. This interaction is a key factor for those with acid sensitivities who want to enjoy their daily brew without discomfort.

Quick Summary

Black coffee is naturally acidic, with a pH between 4.85 and 5.4, while milk has a more neutral pH of 6.5 to 6.8. Adding milk increases the overall pH of the mixture, making the coffee less acidic and potentially easier on the stomach. The final pH depends on the ratio of milk to coffee, with more milk resulting in a higher, less acidic pH.

Key Points

  • Black Coffee's pH: Black coffee is mildly acidic, typically having a pH range of 4.85 to 5.4 due to various natural acids.

  • Milk's pH: Milk has a pH closer to neutral, usually between 6.5 and 6.8, and contains natural buffering agents like proteins and calcium.

  • Milk Neutralizes Acidity: Adding milk to black coffee increases the mixture's overall pH, making it less acidic and smoother to drink.

  • Roast and Brew Influence pH: Darker roasts and cold brew methods naturally produce a less acidic coffee compared to lighter roasts and hot brews.

  • Buffering vs. Dilution: Milk's proteins actively buffer the coffee's acidity, which is more effective for reducing acidity than just simple dilution.

  • Tips for Low Acid Coffee: To reduce acidity, use darker roasts, cold brew, or add dairy/plant-based milk. Paper filters can also help trap acidic oils.

In This Article

The Acidic Nature of Black Coffee

Black coffee is well-known for its acidic properties, which contribute to its bright, complex flavor profile. The pH of black coffee typically ranges from 4.85 to 5.4. This acidity comes from various natural organic acids present in the coffee beans, including:

  • Chlorogenic acids: These are a major component in green coffee beans and break down during roasting.
  • Quinic acid: A byproduct of roasting, which can contribute to a more bitter, astringent taste.
  • Citric and Malic acids: These are responsible for the fruity and tart notes found in some coffee varieties.

Several factors can influence the final acidity of a cup of black coffee:

  • Roast Level: Darker roasts generally have lower acidity, as the roasting process breaks down more of the acidic compounds.
  • Bean Type: Arabica beans tend to have a higher acidity than Robusta beans.
  • Brewing Method: Cold brewing, which involves steeping grounds in cold water for an extended period, is known to produce a less acidic concentrate compared to hot brewing methods.

How Milk Affects Coffee's pH

Milk, on the other hand, has a pH that is much closer to neutral, typically ranging from 6.5 to 6.8. This is due to its protein and calcium content, which act as natural buffering agents. When milk is added to black coffee, its higher pH and buffering capacity work to neutralize the coffee's acidity, resulting in a higher overall pH for the mixed beverage. This is why adding milk can make coffee taste smoother and feel less harsh on the stomach for some people.

Comparison of pH Levels

To illustrate the difference, consider the following approximate pH ranges for common coffee preparations and related beverages. The pH scale is logarithmic, meaning a single-digit change represents a tenfold change in acidity.

Beverage Approximate pH Range Acidity Level
Lemon Juice 2.0–2.6 Highly Acidic
Soda (Coca-Cola) 2.5–3.0 Highly Acidic
Black Coffee 4.85–5.4 Moderately Acidic
Coffee with Milk ~6.0–6.5 Slightly Acidic
Milk 6.5–6.8 Slightly Acidic to Neutral
Distilled Water 7.0 Neutral
Baking Soda Solution 9.0–10.0 Alkaline

The Science of Dilution and Buffering

Adding milk to coffee doesn't just dilute the acids; the proteins and minerals within the milk actively buffer the coffee's pH. Casein and other milk proteins bind with hydrogen ions, effectively raising the pH level. For those with acid reflux or sensitive stomachs, this buffering action can be more beneficial than simple dilution. It is why a latte, with its higher milk content, is often considered a lower-acid option than a simple cup of coffee with a splash of milk.

Practical Tips for Reducing Coffee Acidity

If you find black coffee too acidic, there are several methods to help you enjoy a less acidic cup, with or without milk:

  • Choose a Darker Roast: As previously mentioned, the longer roasting process of dark roasts breaks down more of the acidic compounds, leading to a smoother flavor.
  • Opt for Cold Brew: The cold water extraction method produces a concentrate that is naturally less acidic and bitter.
  • Add Dairy or Dairy Alternative: Milk, cream, and even alkaline plant-based milks like almond or soy can help neutralize the acidity.
  • Change Your Filter: Using a paper filter instead of a metal one can trap some of the acidic oils during the brewing process.
  • Add a Pinch of Baking Soda: For a quick, at-home fix, a tiny pinch of baking soda can act as a neutralizer, though care must be taken not to alter the taste significantly.
  • Consider Low-Acid Brands: Some coffee brands specialize in low-acid beans, often sourced from specific regions or processed with techniques designed to reduce acidity.

Conclusion

Understanding what is the pH of black coffee and milk reveals a clear chemical interaction that has a practical effect on your daily brew. Black coffee is moderately acidic, with a pH typically between 4.85 and 5.4. Milk, being much closer to neutral at around 6.5 to 6.8, acts as a natural buffer when added, increasing the coffee's pH and creating a smoother, less acidic beverage. This simple combination is a reliable solution for anyone seeking to reduce coffee's bite, whether for taste preference or digestive comfort. By controlling the roast, brew method, and additives, you can customize your cup to suit your specific needs and preferences.

Choosing the Right Brew for You

Personal preference and physical sensitivity play major roles in determining the ideal coffee pH. If you experience heartburn or other gastrointestinal issues, moving towards a less acidic brew is a wise choice. The variety of roasts and brewing methods available today, combined with the neutralizing effect of milk, means you don't have to sacrifice flavor for comfort. For those looking to explore different options, resources from specialty roasters can offer guidance on low-acid bean varieties and preparation techniques. Experimenting with these variables allows you to find a perfect balance between flavor and gentleness.

Frequently Asked Questions

Yes, adding milk to coffee makes it less acidic. Milk has a higher pH (closer to neutral) than black coffee, and its proteins and calcium act as natural buffers to neutralize some of the coffee's acidity.

The pH of black coffee typically falls within a mildly acidic range of 4.85 to 5.4. However, this can vary based on factors like bean type, roast level, and brewing method.

The pH of cow's milk is slightly acidic to nearly neutral, generally ranging from 6.5 to 6.8. Its pH can vary slightly depending on factors such as cow diet and processing.

Yes, cold brew coffee is generally less acidic than hot-brewed coffee. The cold water extraction method used for cold brew extracts fewer of the acidic compounds from the coffee grounds.

Darker roasts are typically less acidic than lighter roasts. The high temperatures and longer duration of dark roasting break down more of the acidic compounds in the beans.

Yes, adding a very small pinch of baking soda to your coffee can help neutralize its acidity due to baking soda being an alkaline substance. It is important to use a tiny amount to avoid significantly altering the taste.

Coffee's acidity can be a problem for people with sensitive stomachs, acid reflux, or other digestive issues, as it can worsen symptoms like heartburn. Adjusting the pH can make it more tolerable.

Medical Disclaimer

This content is for informational purposes only and should not replace professional medical advice.