The Core Concept of Iodine Value
The iodine value (IV) is a fundamental analytical parameter in food science for fats and oils. It represents the grams of iodine absorbed by 100 grams of a fat or oil, indicating the degree of unsaturation through the number of double bonds in the fatty acids. A higher IV signifies more unsaturated bonds. For ghrita (clarified butter), the IV is influenced by factors like the source animal, diet, season, and processing, offering insights into its chemical composition and quality.
Standard Ranges and Variations in Ghrita
Pure cow and buffalo ghrita have established IV ranges, though they can vary geographically and seasonally. Cow ghee typically shows a higher IV (around 38.69) compared to buffalo ghee (around 34.10), attributed to differences in unsaturated fatty acids. Dietary factors, such as feeding cottonseed, can increase the IV. Similarly, the inclusion of medicinal herbs in Ayurvedic preparations like Brahmi Ghrita can alter the IV.
The Role of Iodine Value in Adulteration Detection
The IV is a key tool for detecting ghrita adulteration. Because adulterants like cheaper vegetable oils have different IVs, their addition changes the overall IV of the ghrita. Fats like palm olein and sheep body fat, with higher IVs than pure ghrita, will increase the sample's IV. While useful for initial checks, the IV alone may not detect all adulterants, necessitating advanced techniques like fractionation for higher sensitivity.
Factors Influencing Ghrita's Iodine Value
The iodine value of ghrita is influenced by the source animal (cow vs. buffalo), diet (e.g., cottonseed), season, region, processing method, and medicinal ingredients in Ayurvedic preparations. For example, cow ghee generally has a higher IV than buffalo ghee.
Ghee Adulteration Detection: IV and Other Parameters
| Parameter | Pure Cow Ghee | Pure Buffalo Ghee | Ghee + Palm Olein | Ghee + Sheep Fat | 
|---|---|---|---|---|
| Iodine Value (IV) | ~35.5 - 41.2 | ~30.1 - 36.4 | Increases significantly | Increases significantly | 
| Saponification Value | ~210 - 233 | ~210 - 233 | Decreases with adulteration | Decreases with adulteration | 
| Reichert-Meissl (RM) Value | ~26 - 32 | ~32+ | Lowered | Lowered | 
| Butyro-Refractometer (BR) Reading | Varies by region | Varies by region | Increases | Increases | 
This table shows how different parameters change when ghrita is adulterated with fats like palm olein or sheep fat. Using multiple tests alongside the IV provides a more reliable method for detecting adulteration. Advanced techniques can also enhance detection sensitivity.
Conclusion
The iodine value is a critical measure of ghrita's quality and authenticity, reflecting its fatty acid unsaturation. This value is influenced by factors like the animal source, diet, season, and processing. It is a key parameter for quality control and detecting adulteration, helping to ensure consumers receive pure ghrita.
For further details on analyzing adulterated ghrita, refer to {Link: ResearchGate https://www.researchgate.net/publication/311494429_Iodine_value_integrated_with_solvent_fractionation_technique_as_a_tool_for_detecting_palm_olein_and_sheep_body_fat_adulteration_in_ghee_clarified_milk_fat}.